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Joined 3 years ago
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Cake day: June 29th, 2023

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  • Ah, voluntoldment. We just had a big round at my workplace, but at least no one only a couple people up the chain are engaging with the autofellatory fiction that AI will pick up the slack. Even still, they canned the hypercompetent plant engineer that everyone liked, so half his team left and a couple of our projects are dead in the water because of it. /vent

    edit: chemical manufacturing, not software





  • I was on arch as a vestige from my school days, having never quite found the time to switch to something more stable. When I saw the news over the weekend, I checked and found 1 would-be-infected package on my machine that was thankfully months out of date. I’m well past the point of wanting to examine PKGBUILDs every time (hence the out of date package). But, instead of just removing AUR packages and sticking to arch repos, I decided to sweep up the technical debt by wiping and installing Fedora. I’m liking it so far, minus the absolute pain in the ass that is Nvidia on Linux. Fuck academics and their insistence on writing everything targeting CUDA; otherwise, I’d have saved a good bit of money a few years ago with a much more compatible AMD card.





  • No dunking, and make sure what you’re buying is mostly alcohol (> 95%) and not water/alcohol mixtures often used for disinfection. Using in combination with e.g., a toothbrush is probably your best bet. IPA (and acetone) can strip some adhesives and cause certain kinds of electrical insulation to swell or dissolve, so a targeted approach is better. IPA is flammable (though less so than acetone), so be careful/well ventilated when allowing parts to dry, and ensure parts are fully dried before reconnecting to power.

    IPA itself is only about twice as toxic as ethanol and certainly less problematic by inhalation than tar in the long run. I wouldn’t bother with a mask mostly because it won’t do shit unless it’s a cartridge respirator. However, IPA can sometimes facilitate skin absorption. IDK specifically about tar buildup but recommend wearing gloves (disposable nitrile is fine).


  • Do not power law fit your process data for predictive models. No. Stop. Put the keyboard down. Your model will almost certainly fail to extrapolate beyond the training range. Instead, think for at least two seconds about the chemistry and the process, maybe review your kinetics textbook, and only then may you fit to a physics-based model for which you will determine proper statistical significance. Poor fit? Too bad, revise your assumptions or reconsider whether your “data” are really just noise.

    Always run qNMR with an internal standard if you are using it to determine purity. And, as a corollary, do not ignore unidentified peaks. Yes, even if it “has always been that way”.

    DOE models almost certainly tell you less than you think they do, especially when cross-terms are involved, or when the effects are categorical, or when running a fractional factorial design…



  • Ugh I had an older colleague, a PhD organic chemist, who was absolutely convinced that soy would make me (m) infertile. I ordered tofu once when out to lunch and he would not stop warning me to “be careful” and to be mindful of starting a family and “you know those studies.” When I mentioned that the consensus was at best inconclusive and most likely there is no such link, he said that no, “they” definitely showed that excess soy is bad and that he worried about my reproductive health. Like dude even if eating tofu did cause reproductive health issues, mine is none of your goddamn business. On the other hand, the same guy is also convinced that BPA (another estrogen mimic used esp. in certain plastics) concerns are a total hoax because “they did bad science because their sample containers had BPA in them and it leached into the urine samples giving false positive.” Also something about the only evidence of it binding like estrogen was that someone glanced at a crystal structure and halfassedly thought it looked like it might fit and rolled with it for career reasons. Like, I don’t know, man, maybe a couple studies used containers made with BPA, but most probably didn’t. I haven’t read them, but I know you didn’t, either. Also, you’re literally a petrochemist, you know BPA is mostly used in polycarbonates, and lab plastics, especially for analytical work, are mostly polypropylene or polyethylene designed to avoid exactly this kind of leaching. Honestly.






  • Something something typical US circuits can deliver less power than typical Euro circuits. Not a lot less though. Turns out it depends, but the power rating in the EU is in theory usually about 2x that of US circuits, assuming similar current draws.

    I used to own a $15 plastic electric kettle, but it died after a year or two. When I went to target to get a new (hopefully better) one, I realized I could instead buy a plug-in induction plate on sale for $50, and a plain stainless steel kettle that somehow cost only $1.50 (less than the shitty bread that I was also buying? how?). The induction plate was honestly one of the best purchases I’ve made in a long time. Sure, I have to wear earplugs to tolerate the high-pitched scream that the frequency driver makes, but it boils water just as well as an electric kettle and is also soooo much nicer to cook on than the resistive curlicue burners that came with my apartment.




  • ornery_chemist@mander.xyztoMemes@sopuli.xyzWhy
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    1 year ago

    For those who did a search only to get back pages of less-than-useless SEO slop that just recites the number line, here is something that better describes some of the grammatical insanity.

    also, czterydzieści cztery is imo one of the less pronounceable words (well, two of them) in Polish.